About this Journal

Online ISSN: 1521-3773    Print ISSN: 1433-7851
Angewandte Chemie
Volume 39, Issue 21, 2000.

© 2000 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany

 

PDF  3721  Cover Picture
Anja Schwögler, Lars T. Burgdorf, Thomas Carell

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3721::AID-ANIE3721>3.0.CO;2-L

 Review
 
PDF  3740-3749  Organoselenium Chemistry in Stereoselective Reactions
Thomas Wirth

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3740::AID-ANIE3740>3.0.CO;2-N

PDF  3750-3771  Wherefore Art Thou Copper? Structures and Reaction Mechanisms of Organocuprate Clusters in Organic Chemistry
Eiichi Nakamura, Seiji Mori

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3750::AID-ANIE3750>3.0.CO;2-L

PDF  3772-3789  Ionic Liquids - New Solutions for Transition Metal Catalysis
Peter Wasserscheid, Wilhelm Keim

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3772::AID-ANIE3772>3.0.CO;2-5

 Correspondence
 
PDF  3791-3794  On Closed-Shell Interactions, Polar Covalences, d Shell Holes, and Direct Images of Orbitals: The Case of Cuprite
J. M. Zuo, M. O'Keeffe, M. Kim, J. C. H. Spence

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3791::AID-ANIE3791>3.0.CO;2-7

PDF  3794-3796  Final Comment on the Discussions of The Case of Cuprite
Shu Guang Wang, W. H. Eugen Schwarz

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3794::AID-ANIE3794>3.0.CO;2-Q

 Highlight
 
PDF  3797-3800  Stable Systems with a Triple Bond to Silicon or Its Homologues: Another Challenge
Peter Jutzi

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3797::AID-ANIE3797>3.0.CO;2-8

 Communication
 
PDF  3801-3804  Monosaccharide-Alkyl Glycoside Glass Phases: Plasticization with Hydrophilic and Hydrophobic Molecules
Iqbal Gill, Rao Valivety

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3801::AID-ANIE3801>3.0.CO;2-J

PDF  3804-3808  Enzymatic Glycosylation in Plasticized Glass Phases: A Novel and Efficient Route to O-Glycosides
Iqbal Gill, Rao Valivety

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3804::AID-ANIE3804>3.0.CO;2-1

PDF  3808-3810  (CN3H6)4[Zn3(SeO3)5]: The First Organically Templated Selenite
William T. A. Harrison, Mark L. F. Phillips, Jesse Stanchfield, Tina M. Nenoff

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3808::AID-ANIE3808>3.0.CO;2-E

PDF  3810-3813  Correlation of the Topology of the Electron Density of Pyrite-Type Transition Metal Sulfides with Their Catalytic Activity in Hydrodesulfurization
Yosslen Aray, Jesus Rodriguez, David Vega, Eloy Nouel Rodriguez-Arias

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3810::AID-ANIE3810>3.0.CO;2-N

PDF  3813-3816  Higher Adducts of C60 by Tether-Directed Remote Functionalization: X-Ray Crystal Structure and Reactivity of a Chiral Hexakis-Cyclopropanated Fullerene with all Addends Located along an Equatorial Belt
Craig R. Woods, Jean-Pascal Bourgeois, Paul Seiler, François Diederich

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3813::AID-ANIE3813>3.0.CO;2-5

PDF  3816-3819  High-Throughput Structure Verification of a Substituted 4-Phenylbenzopyran Library by Using 2D NMR Techniques
Harald Schröder, Peter Neidig, Gérard Ross?br>
Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3816::AID-ANIE3816>3.0.CO;2-O

PDF  3819-3822  Molecular Topology: Easy Self-Assembly of an Organometallic Doubly Braided [2]Catenane
Christopher P. McArdle, Jagadese J. Vittal, Richard J. Puddephatt

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3819::AID-ANIE3819>3.0.CO;2-6

PDF  3823-3828  Target-Accelerated Combinatorial Synthesis and Discovery of Highly Potent Antibiotics Effective Against Vancomycin-Resistant Bacteria
K. C. Nicolaou, Robert Hughes, Suk Young Cho, Nicolas Winssinger, Christian Smethurst, Harald Labischinski, Rainer Endermann

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3823::AID-ANIE3823>3.0.CO;2-3

PDF  3829-3831  Photoinduced Electron Transfer from a Porphyrin to an Electron Acceptor in an Antibody-Combining Site
Hiroyasu Yamaguchi, Mikiharu Kamachi, Akira Harada

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3829::AID-ANIE3829>3.0.CO;2-4

PDF  3831-3835  Hexagonal Layered Materials Composed of [M2(O2CCF3)4] (M=Ru and Rh) Donors and TCNQ Acceptors
Hitoshi Miyasaka, Cristian S. Campos-Fernández, Rodolphe Clérac, Kim R. Dunbar

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3831::AID-ANIE3831>3.0.CO;2-D

PDF  3835-3839  Supramolecular Chemistry of Anionic Cobalt(iii) Bis(dicarbollide) and Cyclotriveratrylene in the Solid State and the Gas Phase
Michaele J. Hardie, Colin L. Raston

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3835::AID-ANIE3835>3.0.CO;2-Q

PDF  3839-3842  Novel Oligosaccharide Binding to the Cerium(iv) Bis(porphyrinate) Double Decker: Effective Amplification of a Binding Signal through Positive Homotropic Allosterism
Atsushi Sugasaki, Masato Ikeda, Masayuki Takeuchi, Seiji Shinkai

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3839::AID-ANIE3839>3.0.CO;2-2

PDF  3843-3845  Open Square-Grid Coordination Polymers of the Dimensions 20?0 ? Remarkably Stable and Crystalline Solids Even after Guest Removal
Kumar Biradha, Yoshito Hongo, Makoto Fujita

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3843::AID-ANIE3843>3.0.CO;2-#

PDF  3845-3848  The Electrical Properties of Gold Nanoparticle Assemblies Linked by DNA
So-Jung Park, Anne A. Lazarides, Chad A. Mirkin, Paul W. Brazis, Carl R. Kannewurf, Robert L. Letsinger

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3845::AID-ANIE3845>3.0.CO;2-O

PDF  3849-3851  Rapid, Reversible Oxygen Atom Transfer between an Oxomanganese(v) Porphyrin and Bromide: A Haloperoxidase Mimic with Enzymatic Rates
Ning Jin, James L. Bourassa, Steven C. Tizio, John T. Groves

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3849::AID-ANIE3849>3.0.CO;2-0

PDF  3851-3855  The High-Valent Compound of Cytochrome P450: The Nature of the Fe-S Bond and the Role of the Thiolate Ligand as an Internal Electron Donor
François Ogliaro, Shimrit Cohen, Michael Filatov, Nathan Harris, Sason Shaik

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3851::AID-ANIE3851>3.0.CO;2-9

PDF  3855-3859  Formation of Novel Ordered Mesoporous Silicas with Square Channels and Their Direct Observation by Transmission Electron Microscopy
Tatsuo Kimura, Takayuki Kamata, Minekazu Fuziwara, Yuri Takano, Mizue Kaneda, Yasuhiro Sakamoto, Osamu Terasaki, Yoshiyuki Sugahara, Kazuyuki Kuroda

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3855::AID-ANIE3855>3.0.CO;2-M

PDF  3859-3862  Second-Order Nonlinear Optical Properties of Functionalized Ionophores: Cation-Steered Modulation of the First Hyperpolarizability
Stephan Houbrechts, Yuji Kubo, Tomokazu Tozawa, Sumio Tokita, Tatsuo Wada, Hiroyuki Sasabe

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3859::AID-ANIE3859>3.0.CO;2-Z

PDF  3862-3865  Self-Assembled Organometallic Block Copolymer Nanotubes
Jose Raez, Raluca Barjovanu, Jason A. Massey, Mitchell A. Winnik, Ian Manners

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3862::AID-ANIE3862>3.0.CO;2-1

PDF  3866-3868  A Three-Step Entry to the Aspirochlorine Family of Antifungal Agents
Zhicai Wu, Lawrence J. Williams, Samuel J. Danishefsky

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3866::AID-ANIE3866>3.0.CO;2-E

PDF  3868-3872  Ion-Specific Aggregation in Conjugated Polymers: Highly Sensitive and Selective Fluorescent Ion Chemosensors
Jinsang Kim, D. Tyler McQuade, Sean K. McHugh, Timothy M. Swager

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3868::AID-ANIE3868>3.0.CO;2-2

PDF  3872-3873  [{Ir(5-C5Me5)(CO)}6Hg8][CF3CO2]6, a Mixed-Metal Cluster with an Ir6Hg6 Twelve-Membered Ring and Additional Hg Centers and Metal-Metal Bonds
Giuseppina Chiaradonna, Giovanni Ingrosso, Fabio Marchetti

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3872::AID-ANIE3872>3.0.CO;2-#

PDF  3874-3876  Synthesis of Thymine Glycol Containing Oligonucleotides from a Building Block with the Oxidized Base
Shigenori Iwai

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3874::AID-ANIE3874>3.0.CO;2-O

PDF  3876-3879  A Concise Stereoselective Route to the Pentacyclic Frameworks of Arisugacin A and Territrem B
Luke R. Zehnder, Richard P. Hsung, Jiashi Wang, Geoffrey M. Golding

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3876::AID-ANIE3876>3.0.CO;2-C

PDF  3879-3881  Formation of the Unprecedented Trilithio-Capped Heteroadamantanyl Iminoalane Anion [(HAl)4(NPh)6{Li(OEt2)}3]-: An Open Cage Derived from a Rhombododecahedron
Kenneth W. Henderson, Alan R. Kennedy, Arlene E. McKeown, Robert E. Mulvey

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3879::AID-ANIE3879>3.0.CO;2-V

PDF  3881-3884  New Fused Bicyclic Cyclotrigermanes from Cycloaddition Reactions of Cyclotrigermene
Norihisa Fukaya, Masaaki Ichinohe, Akira Sekiguchi

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3881::AID-ANIE3881>3.0.CO;2-3

PDF  3884-3886  Direct Bromination of Keggin Fragments To Give [PW9O28Br6]3-: A Polyoxotungstate with a Hexabrominated Face
R. John Errington, Richard L. Wingad, William Clegg, Mark R. J. Elsegood

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3884::AID-ANIE3884>3.0.CO;2-M

PDF  3886-3888  Control of Xanthine Oxidase Activity by Light
Lin Ai Tai, Kuo Chu Hwang

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3886::AID-ANIE3886>3.0.CO;2-A

PDF  3889-3890  Highly Enantioselective Rh-Catalyzed Hydrogenation Reactions Based on Chiral Monophosphite Ligands
Manfred T. Reetz, Gerlinde Mehler

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3889::AID-ANIE3889>3.0.CO;2-T

PDF  3891-3893  Super-High-Throughput Screening of Enantioselective Catalysts by Using Capillary Array Electrophoresis
Manfred T. Reetz, Klaus M. Kühling, Alfred Deege, Heike Hinrichs, Detlev Belder

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3891::AID-ANIE3891>3.0.CO;2-1

PDF  3894-3896  Novel Nickel(ii) Complexes for the Catalytic Copolymerization of Ethylene and Carbon Monoxide: Polyketone Synthesis in Supercritical Carbon Dioxide
Wolfgang Kläui, Jochen Bongards, Guido J. Rei?br>
Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3894::AID-ANIE3894>3.0.CO;2-K

PDF  3896-3898  A Soluble Polymer-Bound Ruthenium Carbene Complex: A Robust and Reusable Catalyst for Ring-Closing Olefin Metathesis
Qingwei Yao

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3896::AID-ANIE3896>3.0.CO;2-8

PDF  3898-3901  Synthesis and Application of a Permanently Immobilized Olefin-Metathesis Catalyst
Stephan C. Schürer, Simon Gessler, Nicole Buschmann, Siegfried Blechert

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3898::AID-ANIE3898>3.0.CO;2-X

PDF  3901-3905  Speciation in Solution: Silicate Oligomers in Aqueous Solutions Detected by Mass Spectrometry
Patrick Bussian, Frank Sobott, Bernhard Brutschy, Wolfgang Schrader, Ferdi Schüth

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3901::AID-ANIE3901>3.0.CO;2-D

PDF  3905-3909  Stepwise Assembled Photoactive Films Containing Donor-Linked Fullerenes
Chuping Luo, Dirk M. Guldi, Michele Maggini, Enzo Menna, Simonetta Mondini, Nicholas A. Kotov, Maurizio Prato

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3905::AID-ANIE3905>3.0.CO;2-Q

PDF  3909-3911  Breaking the Rule: Synthesis and Molecular Structure of Dinuclear Rhodium Complexes with Bridging and Semibridging Trialkylphosphane Ligands
Thomas Pechmann, Carsten D. Brandt, Helmut Werner

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3909::AID-ANIE3909>3.0.CO;2-2

PDF  3912-3915  Cisplatin Changes the Mechanics of Single DNA Molecules
Rupert Krautbauer, Hauke Clausen-Schaumann, Hermann E. Gaub

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3912::AID-ANIE3912>3.0.CO;2-5

PDF  3915-3917  Spherical Aromaticity in Ih Symmetrical Fullerenes: The 2(N+1)2 Rule
Andreas Hirsch, Zhongfang Chen, Haijun Jiao

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3915::AID-ANIE3915>3.0.CO;2-O

PDF  3918-3920  Self-Repairing DNA Based on a Reductive Electron Transfer through the Base Stack
Anja Schwögler, Lars T. Burgdorf, Thomas Carell

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3918::AID-ANIE3918>3.0.CO;2-6

PDF  3921-3922  Room Temperature Oxidation of Carbon Monoxide Catalyzed by Hydrous Ruthenium Dioxide
Ling Zang, Horst Kisch

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3921::AID-ANIE3921>3.0.CO;2-9

PDF  3923-3925  The Cl4+ Ion
Stefan Seidel, Konrad Seppelt

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3923::AID-ANIE3923>3.0.CO;2-Y

PDF  3925-3929  [{Ag(tBuNH2)2}4][{Ag(tBuNH2)(tBuN=CHCH3)}2][Ag12(CF3CO2)14]: A Compound with an Ag128+ Cluster Core
Peter Rei? Florian Weigend, Reinhart Ahlrichs, Dieter Fenske

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3925::AID-ANIE3925>3.0.CO;2-M

PDF  3929-3933  Synthesis, Crystal Structure, and Binding Properties of the Mixed Valence Clusters [Cu32As30(dppm)8] and [Cu26Te12(PEt2Ph)12]
Reinhart Ahlrichs, Jörn Besinger, Andreas Eichhöfer, Dieter Fenske, Axel Gbureck

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3929::AID-ANIE3929>3.0.CO;2-Z

PDF  3933-3935  A Blue Luminescent Starburst Molecule and Its Orange Luminescent Trinuclear PdII Complex: 1,3,5-tris(7-azaindol-1-yl)benzene (tabH) and [PdII3(tab)2Cl4]
Qingguo Wu, Andrea Hook, Suning Wang

Published Online: 27 Oct 2000
DOI10.1002/1521-3773(20001103)39:21<3933::AID-ANIE3933>3.0.CO;2-W



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